A/Z Notation (Advanced Concept)

Concept sheet | Science and Technology

A/Z Notation of Atoms

Definition

A/Z notation is used to distinguish isotopes of the same element. It displays the symbol of the element (|X|), its atomic number (|Z|), and its mass number (|A|).

A/Z notation has the following structure:

A/Z notation highlights the mass number (A), the atomic number (Z), and the element symbol (X). It, therefore, allows us to know the number of protons, neutrons, and electrons of an element.

The following table summarizes the information that A/Z notation provides regarding the composition of atoms in terms of the number of neutrons, protons, and electrons. Two isotopes of carbon, namely carbon |12| and carbon |13|, are chosen to illustrate their composition.

 

Carbon 12

Carbon 13

A/Z isotope notation

|_{6}^{12}\text{C}|

|_{6}^{13}\text{C}|

Mass number
(A = number of protons + number of neutrons)

|12|

|13|

Atomic number
(Z = number of protons)

|6|

|6|

Number of neutrons
(|N = A-Z|)

|6|

|7|

Number of electrons

|6|

|6|

We see that the atomic number (|Z|) from |2| carbon isotopes is |6|, as they both have |6| protons. In fact, the number of protons of an atom never changes. Carbon isotopes, therefore, always have |6| protons in their nucleus.

Also, because atoms are neutral, they both have the same number of electrons as protons. So there are |6| protons and |6| electrons. Positive charges and negative charges cancel each other out.

On the other hand, the mass number (|A|) varies (either |12|, or |13|), as the isotopes of the same element do not have the same number of neutrons (here, |6| and |7| neutrons).

Example

The A/Z notation for an oxygen isotope is as follows: |_{8}^{17}\text{O}|.
What is the composition of this isotope (number of protons, neutrons, and electrons)?

See solution

Example

What is the A/Z notation for magnesium-|26|?

See solution

Example

An isotope of palladium consists of |46| protons, |46| electrons, and |62| neutrons. What is the A/Z notation for this isotope?

See solution

Sometimes the distribution of electrons is added to A/Z notation.

Example

The A/Z notation for oxygen-|16| with its electronic distribution is noted as follows: |_{8}^{16}\text{O}:2e^{-},6e^{-}.|

A/Z Notation of Ions

A/Z notation can also be applied to ions. The only difference with neutral atoms is that the charge is indicated at the top right of the symbol, for example |_{11}^{23}\text{Na}^+| or |_{17}^{35}\text{Cl}^-|.

To illustrate this, the following table shows the composition of carbon-|12| when it is neutral, positive, or negative.

Atom / Ion Number of neutrons Number of protons Number of electrons
|_{6}^{12}\text{C}| |6| |6| |6|
|_{6}^{12}\text{C}^+| |6| |6| |5|
|_{6}^{12}\text{C}^-| |6| |6| |7|
Important!

All carbon atoms have |6| protons. When the charge of carbon changes, the number of protons always remains the same; the number of electrons is the varying element. When there are more electrons than protons, the ion is negative (e.g., charge |1-| , |2-| , |3-| , etc). When there are fewer electrons than protons, the ion is positive (e.g., charge |1+|, |2+|, |3+|, etc).